By default we ship clpeak on ChromeOS test builds so you do not need to build the binaries yourself simply run /usr/local/opencl/clpeak you should see output similar to this : https://github.com/krrishnarraj/clpeak#sample
If you wish to build once you have a ChromeOS checkout and chroot working just follow these simple instructions:
emerge-${BOARD} clpeak
cros deploy clpeak
ssh /usr/local/opencl/clpeak